Hydrocolloids:
Stabilisers, Thickeners and Gelling Agents > XANTHAN
XANTHAN
Application
Xanthan can be found
in many food applications. It is most often found in salad
dressings and sauces where
it provides a high viscosity at rest and a high pseudoplasticity,
and also good suspension of particles. It is also used
in
Dairy products in combination with other hydrocolloids,
in icecream to control crystal formation, give slow meltdown
and modify and improve textures.
Xanthan provides good
stablisation
of air cells in whipped products like cream and mousse.
Xanthan gives fast hydration, thickening, suspension and
body, to instant mixes, like soups, drinks and desserts.
and beverages.
Xanthan can also be found bakery products, syrups, toppings
and fillings.
| APPLICATION |
FUNCTION |
| Oil - Water dressings |
Emulsion stabilisation and Viscosity control. |
| Syrups and toppings |
Viscosity control and cocoa suspension. |
| Baked goods |
Prevents lump formation during kneading and improves
dough homogeneity. |
| Pastry fillings |
Viscosity and syneresis control. |
| Soups, sauces and marinades |
Viscosity control. |
| Whipped creams & mousses |
Air cell stabilisation. |
| Instant mixes |
Rapid thickening, suspension and provides body. |
Information
on Applications of Xanthan in Dressings (ADM)
Information
on Applications of Xanthan in other food products (ADM)
Chemistry
Xanthan gum (E 415) is a
long chain polysaccharide composed of the sugars' glucose,
mannose, and glucuronic
acid. The backbone is similar to cellulose, with added sidechains
of trisacharides (three sugars in a chain). These features
make it interact with itself and with other long chain molecules
to form thick mixtures and gels in water.
It is a slimy gel produced by the bacterium Xanthomonas
campestris, which causes black rot on cruciferous vegetables
such as cauliflower and broccoli. The slime protects the
bacterium from viruses, and prevents it from drying out.
Properties
One of the most remarkable properties of xanthan gum is
its capability of producing a large increase in the viscosity
of a liquid by adding a very small quantity of gum, on
the
order of one percent. In most foods, it is used at 0.5%,
or even as low as 0.05%. The viscosity of xanthan gum solutions
decreases with higher shear rates, this is called pseudoplasticity.
Foods need high viscosity at low shear rates to be stable
but, when consumed, they must not seem thick and heavy
in
the mouth. Due to the pseudoplastic properties of xanthan
gum, it can seem thin in the mouth (fairly high rates of
shear) but still have good stabilisation properties. Unlike
other gums, it is very stable under a wide range of temperatures
and pH.
When mixed with guar gum or locust bean gum, the viscosity
is more than when either one is used alone, so less of each
can be used.
The backbone of Xanthan gum is similar to cellulose, but
the trisaccharide side chains of mannose and glucuronic
acid make the molecule rigid and allow it to form a right-handed
helix.
The secondary structure of the Xanthan molecule, in which
the side chains are 'wrapped around' the cellulose backbone,
explains the unusual resistance of this hydrocolloid to
degradation by acids or bases, high temperatures, freezing
and thawing, enzymes and prolonged mixing.

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