Hydrocolloids:
Stabilisers, Thickeners and Gelling Agents > AGAR
AGAR
Application
Agar is a gelling agent that is most commonly
used in icings, sugar confectionery, canned meat and fish
products, diabetic and health foods and dairy products.
It's use, however, is declining as more effective and often
cheaper gums become more available.
| APPLICATION |
FUNCTION |
| Canned Meat & Fish |
Binds water and forms a gel network around the meat. |
| Icings |
Binds free water and improves icing flexibility. |
| Meringues |
Binds water and prevents weeping during storage. |
| Fermented milk products |
Moisture control. Will not precipitate casein below
its isoelectric point. |
Chemistry
Agar (E406) is an unbranched
polysaccharide obtained from the cell walls of some species
of red algae or seaweed. The
word
agar comes from the Malay word agar-agar (meaning jelly).
Chemically, agar is a polymer made up of subunits of the
sugar galactose. Agar polysaccharides serve as the primary
structural support for the algae's cell walls. Dissolved
in hot water and cooled, agar becomes gelatinous. One of
its chief uses is as a culture medium for microbiological
work.
Properties
Agar is typically sold as packaged strips of washed and
dried seaweed, or in powdered form. Raw agar is white and
semi-translucent.
Agar is insoluble in cold water and requires boiling to
dissolve fully. On cooling, Agar gels between 40°C and
30°C,
depending on concentration and quality. The gel is thermo-reversable
but does not normally melt below 85°C. This difference in
setting and melting temperature can be utilised in certain
food applications, for example when using jelly to coat
fruit flans at low working temperatures.
Agar will form weak gels at very low concentration (0.2%);
rigid gels are formed at concentrations of 0.5%. The maximum
strength is developed approximately one hour after reaching
room temperature. Gels are usually very firm, rigid, slightly
elastic and can have a slightly turbid yellow colouration,
although very high quality transparent agars are available.
Being strong and rigid, the gel is very prone to syneresis.
The addition of Locust Bean gum gives a more elastic gel
with less tendency to syneresis.
Agar is sensitive to acids. Increasing sugar levels to a
maximum of 20% results in an increase in gel strength. At
higher levels, a stiff paste if formed which can be partially
acid-hydrolysed to yield a pipable gel. Also, increasing
the salt concentration increases the strength of the gel.
Agar is stable to retorting but not stable to repeated freezing
and thawing. It is not protein reactive.
An example of Agar use is making jelly. It is boiled in
water at a concentration of about 0.7-1% w/v until the solids
dissolve, after which sweeteners, flavouring, colouring,
and pieces of fruit may be added. The agar-agar may then
be poured into molds or incorporated into other desserts,
such as a jelly layer on a cake.
Role of Agar in the latest Asian fad
diet
One of the latest fad diets in Asia is the Kanten
Diet.
Once ingested, kanten triples in size and absorbs water.
This results in the consumer feeling more full. This diet
has also recently received some press coverage in the United
States. The diet has shown promise in obesity studies,
but
agar/kanten has virtually no nutritional value. It is approximately
80% fibre, so part of the diet's effectiveness may be a
result of it working as a laxative. There are also some
(claimed) effects as to the benefits of agar-agar in controlling
diabetes.

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